RAS Chemistry & Material ScienceТеоретические основы химической технологии Theoretical Foundations of Chemical Engineering

  • ISSN (Print) 0040-3571
  • ISSN (Online) 3034-6053

Synthesis of Complex Esters of Pentaerythritol and Isomeric Carboxylic Acids C

PII
S3034605325050107-1
DOI
10.7868/S3034605325050107
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 59 / Issue number 5
Pages
147-155
Abstract
For the first time, tetraethers of pentaerythritol and carboxylic acids were synthesized: 2-methylpentanoic, 4-methylpentanoic, 2,2-dimethylbutanoic, and 2-ethylbutanoic acids. The main series of ions were obtained during mass spectral analysis of these compounds. The viscosity and melting point indices of the obtained and purified ( wt. %) samples were determined. The kinetic parameters of the esterification of these carboxylic acids with pentaerythritol were studied, and the rate constants for all stages of the hydroxyl group substitution process were determined. The influence of the carboxylic acid structure on the duration of the esterification process was shown.
Keywords
пентаэритрит сложные эфиры константы скорости кинематическая вязкость индекс вязкости
Date of publication
10.09.2025
Year of publication
2025
Number of purchasers
0
Views
21

References

  1. 1. Chen B., Liu L., Zhang C., Zhang S., Zhang Y., & Zhang P. Tribological properties and lubrication mechanism of protic ionic liquid-modified nanosilica as high-temperature antiwear additive for pentaerythritol ester // Tribol. Int. 2022. V. 176. ID 107886.
  2. 2. Xu Z., Lou W., Zhao G., Zhang M., Hao J., Wang X. Pentaerythritol rosin ester as an environmentally friendly multifunctional additive in vegetable oil-based lubricant // Tribol. Int. 2019. V. 135. P. 213.
  3. 3. Wang Y., Liang Y., Li Y., Rui W., He J., Zhao M. Synthesis, tribological properties and oxidative stability of polyol esters base oils containing pentaerythritol complex esters // Tribol. Int. 2024. V. 195. ID 109618.
  4. 4. Li L., Bai P., Wen X., Zhou X., Ma K., Meng Y., Ding J., Tian Y. Wear mechanism and evolution of tribofilm of ceramic on steel pairs under ester oil lubrication in wide temperature range //J. Mater. Res. Technol. 2023. V. 27. P. 6984.
  5. 5. Airey J., Spencer M., Greenwood R., Simmons M. The effect of gas turbine lubricant base oil molecular structure on friction // Tribol. Int. 2020. V. 146. ID 106052.
  6. 6. Громова В.В., Мамарасулова З.В. Термическая этерификация пентаэритрита алифатическими монокарбоновыми кислотами // Известия СПбГТИ (ТУ). 2013. Т. 46. № 20. С. 64.
  7. 7. Gromova V.V. and Mamarasulova Z.V. Thermal esterification of pentaerythritol with aliphatic monocarboxylic acids. Izvestiya SPbGTI (TU). 2013, vol. 46, no. 20, p. 64.
  8. 8. Марочкин Д.В., Носков Ю.Г., Крон Т.Е., Карчевская О.Г., Корнеева Г.А. Продукты оксосинтеза в производстве сложноэфирных смазочных масел // Научно-технический вестник ОАО НК РОСНЕФТЬ. 2016. № 45. С. 74.
  9. 9. Marochkin D.V., Noskov Yu.G., Kron T.E., Karchevskaya O.G., and Korneeva G.A. Oxosynthesis products in the production of ester lubricating oils. Scientific and Technical Bulletin of Rosneft. 2016, no. 45, p. 74.
  10. 10. Konishi M., Washizu H. Understanding the effect of the base oil on the physical adsorption process of organic additives using molecular dynamics // Tribol. Int. 2020. V. 149. ID 105568.
  11. 11. Rudnick L.R. Synthetics, Mineral Oils, and Bio-Based Lubricants. Chemistry and Technology. London: CRC Press, 2020.
  12. 12. Emelyanov V.V., Krasnykh E.L., Fetisov D.A., Levanova S.V., Shakun V.A. Features of the synthesis of pentaerythritol esters and carboxylic acids of aliphatic isomeric structure // Fine Chemical Technologies. 2022. V. 17. № 1. P. 7.
  13. 13. Емельянов В.В., Красных Е.Л., Фетисов Д.А., Леванова С.В., Шакун В.А. Особенности синтеза сложных эфиров пентаэритрита и алифатических карбоновых кислот изомерного строения // Тонкие химические технологии. 2022. Т. 17. № 1. С. 7.
  14. 14. Sun L., Zhu L., Xue W., Zeng Z. Kinetics of p-toluene-sulfonic acid catalyzed direct esterification of pentaerythritol with acrylic acid for pentaerythritol di acrylate production // Chem. Eng. Commun. 2020. V. 207. № 3. P. 331.
  15. 15. Ladero M., Gracia M., Trujillo F., Garcia-Ochoa F. Phenomenological kinetic modelling of the esterification of rosin and polyols // Chem. Eng. J. 2012. V. 197. P. 387.
QR
Translate

Indexing

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library